Glauberite

(repeating unit)Na2Ca(SO4)2IMA symbolGlb[1]Strunz classification7.AD.25Crystal systemMonoclinicCrystal classPrismatic (2/m)
(same H-M symbol)Space groupC2/cUnit cella = 10.129, b = 8.306
c = 8.533 [Å]; β = 112.19°; Z = 4IdentificationColorGray or pale yellow, colorlessCrystal habitTabular prismatic crystalsCleavagePerfect on {001}, imperfect on {110}FractureConchoidalTenacityBrittleMohs scale hardness2.5–3LusterVitreous to waxy, pearly on cleavagesStreakWhiteDiaphaneityTransparent to translucentSpecific gravity2.75–2.85Optical propertiesBiaxial (−)Refractive indexnα = 1.507 – 1.515 nβ = 1.527 – 1.535 nγ = 1.529 – 1.536Birefringenceδ = 0.0222V angle24° to 34°Dispersionstrong r > vSolubilityHCl and H2O (water) solubleAlters toreadily alters to gypsumOther characteristicsoften a pseudomorphReferences[2][3][4]

Glauberite is a monoclinic sodium calcium sulfate mineral with the formula Na2Ca(SO4)2.

It was first described in 1808 for material from the El Castellar Mine, Villarrubia de Santiago, Toledo, Castile-La Mancha, Spain. It was named for the extracted Glauber's salts after the German alchemist Johann Rudolf Glauber (1604–1668).[2]

Glauberite often forms in continental and marine evaporite deposits, but may also form from hydrothermal deposits, as mineral sublimates deposited near fumaroles, in amygdules in basalt, and in nitrate deposits in arid climates. It occurs associated with halite, polyhalite, anhydrite, gypsum, thenardite, mirabilite, sassolite and blodite.[4]

Because of its solubility, glauberite is often dissolved away from the crystal matrix leaving a distinctly shaped hollow cast. Its mineral composition is readily altered into other minerals as pseudomorphs. Gypsum pseudomorphs are common due to increased humidity.

Glauberite, its cast impressions, and its pseudomorphed crystals are often easily recognizable due to its common crystal twinning, and crystal habit displayed by uniquely shaped flattened, often seeming rhombohedral, large individual 'floater crystals'.

The mineral is commercially mined for its sulfate contents.[5]

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Glauberite on Mindat
  3. ^ Glauberite data on Webmineral
  4. ^ a b Glauberite in the Handbook of Mineralogy
  5. ^ Chen, Shuzhao; Zhang, Donghua; Shang, Tao; Meng, Tao (August 2018). "Experimental Study of the Microstructural Evolution of Glauberite and Its Weakening Mechanism under the Effect of Thermal-Hydrological-Chemical Coupling". Processes. 6 (8): 99. doi:10.3390/pr6080099.
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