Manganese arsenide

Manganese arsenide
Names
IUPAC name
Manganese arsenide
Identifiers
CAS Number
  • 12005-95-7 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74705
ECHA InfoCard 100.031.331 Edit this at Wikidata
EC Number
  • 234-478-9
PubChem CID
  • 82783
InChI
  • InChI=1S/Mn.As
    Key: NYOGMBUMDPBEJK-UHFFFAOYSA-N
  • [As].[Mn]
Properties
Chemical formula
MnAs
Molar mass 129.859 g/mol
Structure[1]
Crystal structure
Hexagonal (NiAs)
Space group
P63/mmc (No. 194), hP4
Lattice constant
a = 0.4 nm, c = 0.5702 nm
Formula units (Z)
2
Hazards
Flash point Non-flammable
Related compounds
Other anions
Manganese silicide
Other cations
Gallium arsenide
Nickel arsenide
Related compounds
Gallium manganese arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Manganese arsenide (MnAs) is an intermetallic compound, an arsenide of manganese. It forms ferromagnetic crystals with hexagonal (NiAs-type) crystal structure, which convert to the paramagnetic orthorhombic β-phase upon heating to 45 °C (113 °F). MnAs has potential applications in spintronics, for electrical spin injection into GaAs and Si based devices.[2]

References

  1. ^ Ido, H.; Yasuda, S.; Kido, M.; Kido, G.; Miyakawa, T. (1988). "EFFECT OF HIGH PRESSURE AND HIGH MAGNETIC FIELD ON MAGNETISM OF MnAs1−xSbx (0 ≤ x ≤ 0.3)". Le Journal de Physique Colloques. 49: C8-167-C8-168. doi:10.1051/jphyscol:1988870.
  2. ^ Mocuta, Cristian; Bonamy, Daniel; Stanescu, Stefan; El Moussaoui, Souliman; Barbier, Antoine; Montaigne, François; MacCherozzi, Francesco; Bauer, Ernst; Belkhou, Rachid (2017). "Finite size effect on the structural and magnetic properties of MnAs/GaAs(001) patterned microstructures thin films". Scientific Reports. 7 (1): 16970. Bibcode:2017NatSR...716970M. doi:10.1038/s41598-017-17251-y. PMC 5717107. PMID 29208928.
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Manganese(-I)
  • MnH(CO)5
Manganese(0)
  • Mn2(CO)10
Manganese(I)
  • (C5H4CH3)Mn(CO)3
  • Mn(CO)5Br
Manganese(II)
  • MnC2O4
  • MnO
  • Mn3(PO4)2
  • MnS
  • MnSe
  • MnTe
  • Mn(NO3)2
  • MnCO3
  • MnCl2
  • MnSO4
  • MnF2
  • MnBr2
  • MnI2
  • MnTiO3
  • MnMoO4
  • Mn(CH3COO)2
  • Mn(OH)2
  • MnSe2
  • Mn(ClO3)2
  • Mn(ClO4)2
  • Mn(C5H5)2
  • Mn(C3H5O3)2
  • C
    24
    H
    48
    MnO
    4
  • C
    36
    H
    70
    MnO
    4
Manganese(II,III)
  • Mn3O4
Manganese(II,IV)
  • Mn5O8
Manganese(III)
  • MnCl3
  • Mn2O3
  • MnF3
  • K6Mn2O6
  • MnAs
  • MnPO4
  • Mn(CH3COO)3
Manganese(IV)
Manganese(V)
  • K3MnO4
  • MnF5 (predicted)
Manganese(VI)
  • H2MnO4
  • MnO3
  • Na2MnO4
  • K2MnO4
  • MnO2F2 (predicted)
Manganese(VII)
  • Mn2O7
  • KMnO4
  • MnO3F
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Binary arsenides
AsH3
+H
He
LiAs Be BAs C +N +O F Ne
Na3As Mg AlAs -Si P S +Cl Ar
K CaAs Sc Ti V Cr MnAs Fe CoAs Ni Cu Zn3As2 GaAs -Ge As Se +Br Kr
Rb Sr YAs Zr Nb MoAs2 Tc Ru Rh PdAs2 Ag Cd3As2 InAs -Sn Sb +Te +I Xe
Cs Ba * Lu Hf TaAs WAs2 Re Os Ir Pt Au Hg Tl Pb BiAs Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
* La Ce PrAs Nd Pm SmAs Eu Gd Tb Dy Ho Er Tm Yb
** Ac Th Pa U NpAs
NpAs2
PuAs Am Cm Bk Cf Es Fm Md No
Ternary arsenides
Quaternary arsenides
Quinary arsenides
See also