Ruthenium(IV) fluoride

Ruthenium(IV) fluoride
Names

Other names Ruthenium tetrafluoride
Identifiers
CAS Number	71500-16-8
3D model (JSmol)	Interactive image
ChemSpider	146211
EC Number	238-533-8
PubChem CID	167109
InChI InChI=1S/4FH.Ru/h4*1H;/q;;;;+4/p-4 Key: CBIYWHCPXHKZME-UHFFFAOYSA-J
SMILES [F-].[F-].[F-].[F-].[Ru+4]
Properties
Chemical formula	F₄Ru
Molar mass	177.06 g·mol⁻¹
Appearance	pink crystals
Solubility in water	reacts with water
Structure
Crystal structure	monoclinic
Related compounds
Related compounds	Rhodium tetrafluoride, platinum tetrafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chemical compound

Ruthenium(IV) fluoride is a binary inorganic compound of ruthenium and fluorine with the formula RuF₄.^[1]^[2]

Synthesis

The compound was first prepared in 1963 by Holloway and Peacock, who obtained a yellow solid by reducing ruthenium pentafluoride with iodine, using iodine pentafluoride as a solvent.^[3]

10RuF₅ + I₂ → 10RuF₄ + 2IF₅

Subsequent studies have indicated that RuF
₄ produced by this way is impure. The pure, pink compound was isolated for the first time in 1992 by reacting KRuF
₆ with AsF
₅ at 20 °C in anhydrous hydrofluoric acid, with strict exclusion of water and oxygen. This synthesis exploits the very strong fluoride ion accepting capabilities of the Lewis acid AsF
₅.^[4]^[5]

K₂RuF₆ + 2AsF₅ → RuF₄ + 2KAsF₆

Physical properties

RuF
₄ in the solid state is polymeric, with a three-dimensional structure of corrugated layers containing RuF₆ octahedra joined by shared fluorine atoms. The crystalline structure is similar to that of vanadium tetrafluoride and is monoclinic, space group P2₁/n, with lattice constants a = 560.7 pm, b = 494.6 pm, and c =514.3 pm, β = 121.27°.^[6]

Ruthenium tetrafluoride is an extremely reactive compound which darkens immediately upon contact with moisture, and reacts violently with water to deposit ruthenium dioxide. The compound can be stored in glass containers, which are, however, attacked if the sample is heated above 280 °C.

References

^ Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil (July 1992). "Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride". Inorganic Chemistry. 31 (14): 3124–3131. doi:10.1021/ic00040a024. ISSN 0020-1669. Retrieved 10 April 2023.
^ Bartlett, Neil (2001). The Oxidation of Oxygen and Related Chemistry: Selected Papers of Neil Bartlett. World Scientific. p. 306. ISBN 978-981-281-198-1. Retrieved 10 April 2023.
^ Reactor Fuel Processing. U.S. Argonne National Laboratory. 1963. p. 28. Retrieved 10 April 2023.
^ Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil (July 1992). "Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride". Inorganic Chemistry. 31 (14): 3124–3131. doi:10.1021/ic00040a024. ISSN 0020-1669. Retrieved 10 April 2023.
^ Esteban, G. L.; Kerr, J. A.; Trotman-Dickenson, A. F.; Gronowitz, S.; Katritzky, A. R.; Reavill, R. E.; Ridgewell, B. J.; Green, M.; Hudson, R. F.; Brimacombe, J. S.; How, M. J.; Acheson, R. M.; Miller, G. R.; Plunkett, A. O.; Cavell, R. G.; Clark, H. C.; Holloway, J. H.; Peacock, R. D.; Ebsworth, E. a. V.; Mays, M. J.; Handford, B. O.; Whalley, W. B.; Grundon, M. F.; Reynolds, B. E.; Sayigh, A. a. R.; Ulrich, Henri; Rubinfeld, J.; Palmer, P. J.; Hollingsworth, B. L.; Tuck, D. G.; Bott, R. W.; Eaborn, C.; Hashimoto, T.; Craig, J. Cymerman; Moyle, M.; Tidd, B. K.; Arthur, H. R.; Ollis, W. D.; Greenwood, N. N.; Wallbridge, M. G. H.; Bentley, K. W.; Dyke, S. F.; Marshall, A. R.; Smith, E. E.; Whelan, W. J.; Finan, P. A.; Ahmed, M. T.; Swallow, A. J. (1 January 1963). "Notes". Journal of the Chemical Society (Resumed): 3879–3919. doi:10.1039/JR9630003879. ISSN 0368-1769. Retrieved 10 April 2023.
^ "WebElements Periodic Table » Ruthenium » ruthenium tetrafluoride". webelements.com. Retrieved 10 April 2023.